The game will take place at the MetLife Stadium in New Jersey, USA on November 14 to celebrate the 1000th game of the Brazil national team.
Chelsea host Liverpool in the Premier League on November 11 and travel to West Brom the following weekend.
Totteham midfielder Sandro has also been included in a strong 21-man group, alongside the likes of Kaka, Neymar and Hulk.
Kaka, who has lost his first-team place at Real Madrid, returned to the Brazil squad last month for the first time since 2010.
Squad: Diego Alves (Valencia), Jefferson (Botafogo), Daniel Alves (Barcelona), Thiago Silva (Paris Saint Germain), David Luiz (Chelsea), Leandro Castan (Roma), Rever (Atletico Mineiro), Adriano (Barcelona), Fabio Santos (Corinthians), Paulinho (Corinthians), Sandro (Tottenham Hotspur), Ramires (Chelsea), Arouca (Santos), Kaka (Real Madrid), Giuliano, Lucas (Sao Paulo), Hulk (Zenit St Petersburg), Oscar (Chelsea), Neymar (Santos), Leandro Damiao (Internacional), Thiago Neves (Fluminense).