Bournemouth manager Eddie Howe has vowed to give his promotion heroes the chance to shine in the Premier League.
Wolves boss Kenny Jackett fears he will lose key winger Bakary Sako after his side missed out on a place in the play-offs.
The 29-year-old will go straight into United's squad for the clash with Crystal Palace on Saturday.
Manager Neil Warnock revealed that Thomas was a long-time target of his.
"He's a player I've tried to sign five times so it's about time I finally got him," Warnock told the club's official website. "He is just what I'm looking for and I want him to come here and enjoy himself.
"He's direct and positive when he's attacking and fits the bill as just what we want."
Former Arsenal trainee Thomas has made over 200 career appearances for QPR, Portsmouth, Charlton and West Brom.